Affiliation:
1. Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5 – 13 (Haus D), 81377 München, Germany
Abstract
The cerium meta-oxoborate δ -Ce(BO2)3 was synthesized under high-pressure / high-temperature conditions of 3.5 GPa and 1050 °C in a Walker-type multianvil apparatus. The crystal structure was determined by single crystal X-ray diffraction data, collected at r. t. The compound crystallizes monoclinicly in the space group P21/c with the lattice parameters a = 422.52(8), b = 1169.7(2), c = 725.2(2) pm, and β = 91.33(3)°. The structure is isotypic to the recently published high-pressure phase δ -La(BO2)3, consisting exclusively of corner sharing [BO4]5− tetrahedra
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31 articles.
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