2D and 3D Silver(I)-Ethylenediamine Coordination Polymers with Ag–Ag Argentophilic Interactions-Reference-Cited by-同舟云学术

2D and 3D Silver(I)-Ethylenediamine Coordination Polymers with Ag–Ag Argentophilic Interactions

Published:2007-09-01 Issue:9 Volume:62 Page:1112-1116
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Dai Ji-Xiang¹,Zhu Hai-Liang¹²,Rothenberger Alexander³,Zhang Qian-Feng¹

Affiliation:

1. Department of Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, China

2. Institute of Functional Biomolecules, Nanjing University, Nanjing 210093, China

3. Institut für Anorganische Chemie, Universität Karlsruhe (TH), 76128 Karlsruhe, Germany

Abstract

Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2007-0902/pdf

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1. Synthesis and structural characterisation of some 1:1:2 complexes of silver(I) compounds with triphenylpnictides and “ethylenediamine”, [(Ph3E)(N-en)Ag(N-en-N')2Ag(N-en)(EPh3)]2+(X−)2;Inorganica Chimica Acta;2022-05

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