Unsymmetrical Single-Component Nickel 1,2-Dithiolene Complexes with Extended Tetrachalcogenafulvalenedithiolato Ligands-Reference-Cited by-同舟云学术

Unsymmetrical Single-Component Nickel 1,2-Dithiolene Complexes with Extended Tetrachalcogenafulvalenedithiolato Ligands

Published:2007-02-01 Issue:2 Volume:62 Page:200-204
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Anyfantisa George C.¹,Papavassiliou George C.¹,Aloukos Panagiotis²,Couris Stelios²,Weng Yufeng F.³,Yoshino Harukazu³,Murata Keizo³

Affiliation:

1. Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48, Vassileos Constantinou Ave., Athens 116-35, Greece

2. Institute of Chemical Engineering and High Temperature Chemical Processes (ICE-HT), Foundation for Research and Technology-Hellas (FORTH), Patras 265-04, Greece and Department of Physics, University of Patras, Patras 265-04, Greece

3. Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan

Abstract

The unsymmetrical complexes Ni(dmdt)(dmio) and Ni(dmstfdt)(dmio) (dmdt = dimethyltetrathiafulvalenedithiolate, dmstfdt = dimethyldiselenadithiafulvalenedithiolate, dmio = 1,3-dithiol-2-one- 4,5-dithiolate) were prepared and characterized analytically and spectroscopically. The complexes exhibit strong third-order nonlinear optical response in the visible and near-infrared spectral regions.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2007-0209/pdf

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