Formation of BrO2 in the Belousov-Zhabotinsky-System- Investigation of the Ce3+ /BrO3 --Reaction*-Reference-Cited by-同舟云学术

Formation of BrO2 in the Belousov-Zhabotinsky-System- Investigation of the Ce3+ /BrO3 --Reaction*

Published:1980-03-01 Issue:3 Volume:35 Page:329-331
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Försterling H.-D.¹,Lamberz H.¹,Schreiber H.¹

Affiliation:

1. Fachbereich Physikalische Chemie der Philipps-Universität, Marburg

Abstract

Abstract The reaction between Ce3+ and bromate was studied in sulfuric acid solution using a dual wavelength spectrometer. From the spectral dependence of the absorbance in the region from 450 to 600 nm it is concluded that BrO2 is an intermediate of the reaction. The kinetics of formation and decay of BrO2 is compared to theoretical models.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1980-0310/pdf

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1. Formation of High Concentrations of BrO2 in Acidic Bromate Solutions;Inorganic Chemistry;2004-06-17

2. The role of radicals in the Belousov-Zhabotinsky reaction;Reaction Kinetics and Catalysis Letters;1990-09

3. New strategies for studies on the kinetics and energetics of the Belousov-Zhabotinskii reaction;Berichte der Bunsengesellschaft für physikalische Chemie;1987-12

4. Kinetik chemischer Reaktionen;Moleküle und Molekülanhäufungen;1983

5. Belousov-Zhabotinsky System: Mechanism of the Ce 3+/Bromate Reaction;Nonlinear Phenomena in Chemical Dynamics;1981