Das Spektrum der verzögerten Fluoreszenz in Anthracen-und Naphthalin-Kristallen

Abstract

The spectra of delayed fluorescence of high purity anthracene and naphthalene crystals have been measured as a function of temperature. Below 50 °K they are very different from the spectra of prompt fluorescence. The spectra of delayed fluorescence are the superposition of three types of subspectra: different X-traps-spectra, a broad continuum, and the pure crystal spectrum. From the temperature dependence of the relative intensities of these spectra one can measure the trap depth. - It is shown that the delayed fluorescence is at least 100 times more sensitive against traps and guest molecules than the prompt fluorescence. This is demonstrated using naphthalene-anthracene mixed crystals.