Enantioselective Hydrosilylation with a Chiral N-Heterocyclic Carbene Complex of Rhodium(I) [1]-Reference-Cited by-同舟云学术

Enantioselective Hydrosilylation with a Chiral N-Heterocyclic Carbene Complex of Rhodium(I) [1]

Published:2009-12-01 Issue:11-12 Volume:64 Page:1607-1611
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Zinner Sandra C.¹,Zhang-Preße Mei²,Herrmann Wolfgang A.¹²,Kühn Fritz E.¹³

Affiliation:

1. Chair of Inorganic Chemistry

2. Molecular Catalysis, Catalysis Research Center of the Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany

3. Molecular Catalysis, Catalysis Research Center of the Technische Universität Müchen, Lichtenbergstr. 4, 85747 Garching, Germany

Abstract

Both enantiomers of the chiral rhodium-NHC complex [(4X, 5X)-1,3-bis[2,6-diisopropyl-phenyl]- 4,5-ditert-butylimidazolidine-2-ylidene][1,5-cyclooctadiene]-iodo-rhodium(I) with X = R, S were applied as catalysts for the asymmetric hydrosilylation of prochiral ketones. The influence of employed solvent, substrate, silane, and catalyst enantiomer on the catalytic activity and the enantioselectivity of the desired product was investigated

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2009-11-1246/pdf

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Palladium, iridium, and rhodium complexes bearing chiral N ‐heterocyclic carbene ligands applied in asymmetric catalysis;Applied Organometallic Chemistry;2022-07-13

2. Chiral Imidazo[1,5-a]pyridine–Oxazolines: A Versatile Family of NHC Ligands for the Highly Enantioselective Hydrosilylation of Ketones;Organometallics;2020-01-15

3. Synthesis of Planar Chiral [2.2]Paracyclophanyl Imidazo[1,5-a]pyridinium Salts for the Rhodium-Catalyzed Asymmetric Arylation;Synthetic Communications;2012-12-21

4. Rhodium-Catalyzed Hydrosilylation of Ketones: Catalyst Development and Mechanistic Insights;ACS Catalysis;2012-03-14

5. Synthesis and characterization of chiral mono N-heterocyclic carbene-substituted rhodium complexes and their catalytic properties in hydrosilylation reactions;Journal of Organometallic Chemistry;2011-12