Crystal Structure of the New Ternary Antimonide Ho5GaSb3

Author:

Antonyshyn Iryna1,Zhak Olga1,Oryshchyn Stepan1,Babizhetskyy Volodymyr2,Hoch Constantin2,Aksel’rud Lev1

Affiliation:

1. Department of Analytical Chemistry, Ivan Franko National University of L’viv, Kyrylo & Mefodij Str., 6, 79005 L’viv, Ukraine

2. Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse, 1, Postfach 800665, 70569 Stuttgart, Germany

Abstract

The crystal structure of the new ternary antimonide Ho5GaSb3 has been determined from X-ray single-crystal data: space group Pnma, a = 7.9667(8), b = 15.128(2), c = 7.9616(8) Å , V = 959.5(3) Å3, Z = 4, RF = 0.059, Rw = 0.066 for 9020 reflections. The crystal structure of Ho5GaSb3 is a ternary derivative of the Sm5Ge4 structure type with partially ordered distribution of gallium and antimony atoms

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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