Synthesis, Structure and Electrochemistry of [Ru2(S2CNMe2)3(μ3-S2CNMe2)2]2[Mo6O19]

Synthesis, Structure and Electrochemistry of [Ru2(S2CNMe2)3(μ3-S2CNMe2)2]2[Mo6O19] · 2CH3COCH3

Published:2009-07-01 Issue:7 Volume:64 Page:800-804
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Wu Fang-Hui¹²,Liu Yang-Li²,Lu Lude¹,Zhang Qian-Feng²,Leung Wa-Hung³

Affiliation:

1. Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

2. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, P. R. China

3. Department of Chemistry, The Hong Kong University of Science and Technology, ClearWater Bay, Kowloon, Hong Kong, P. R. China

Abstract

Reaction of MoO2(S2CNMe2)2 with RuCl3 ・χH2O in acetone at reflux afforded [Ru2(S2CNMe2)3- (μ3-S2CNMe2)2]2[Mo6O19]・2CH3COCH3 (1・2CH3COCH3) which was characterized by singlecrystal X-ray diffraction to show a dinuclear ruthenium-dithiocarbamate species as cation and hexamolybdate as counter anion. The [Ru2(S2CNMe2)3(μ3-S2CNMe2)2]+ cation may be considered as a combination of [Ru(S2CNMe2)3] with a cis-[Ru(S2CNMe2)2]+ species, and the Lindqvist anion [Mo6O19]2− is located on an inversion center between two cations. Spectroscopic properties along with the electrochemistry of compound 1・2CH3COCH3 are reported.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2009-0704/pdf

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