Synthesis of the spiroacetal fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113-Reference-Cited by-同舟云学术

Synthesis of the spiroacetal fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113

Published:2015-12-01 Issue:6 Volume:21 Page:337-343
ISSN:2191-0197
Container-title:Heterocyclic Communications
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Author:

Sakauchi Hiroyuki¹,Higashi Emi²,Shimizu Yuko²,Kojima Mikiko²,Asamitsu Yuko²,Kuwahara Shigefumi²,Izumi Minoru¹,Kiyota Hiromasa¹

Affiliation:

1. 1Graduate School of Environmental and Life Science, Okayama University, 1-1-1 Tsushima-Naka, Kita, Okayama 700-8530, Japan

2. 2Graduate School of Agricultural Science, Tohoku University, Japan

Abstract

AbstractThe spiroacetal [C(9)–C(20)] fragments of spirofungins A and B, antibiotics isolated from Streptomyces violaceusniger Tü 4113, were prepared from a known bromo alcohol derived from (S)-citronellal, using thermodynamically controlled iodolactonization and spiroacetalization as the key steps.

Publisher

Walter de Gruyter GmbH

Subject

Organic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/hc-2015-0193/pdf

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