Affiliation:
1. Department of Chemistry, Jadavpur University, Kolkata – 700 032, India
2. Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010 Graz, Austria
Abstract
Two new complexes of manganese(II) and cobalt(II), [Mn(tptz)(OCH3CO)(H2O)2]ClO4 (1) and [Co(tptz) (OSO3) (H2O)2](H2O)2 (2) {where tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine}, have been prepared and characterised by elemental analyses, spectroscopic, electrochemical studies and single crystal X-ray diffraction. Single crystal X-ray analysis reveals complexes of Mn(II) and Co(II), where tptz remains intact and behaves as a tridentate ligand and forms heptacoordinated Mn(II) and hexacoordinated Co(II) complexes for 1 and 2, respectively.
Cited by
27 articles.
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2. Synthesis, crystal structure, antibacterial activity and theoretical studies on a novel mononuclear cobalt(II) complex based on 2,4,6-tris(2-pyridyl)-1,3,5-triazine ligand;Journal of Molecular Structure;2015-08
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