Affiliation:
1. Institut für Anorganische Chemie der Technischen Universität Braunschweig
2. Lehrstuhl für Anorganische Chemie II der Ruhruniversität Bochum
Abstract
KSiH3 in HMPT and monoglyme solutions has been investigated by 1H and 29Si NMR spectroscopy; chemical shifts and coupling constants have been measured. The polysilyl anions H3SiSiH2
⊖, (H3Si)2SiH⊖ and (H3Si)3Si⊖ have been prepared (a) from SiH3
⊖ with excessive SiH4, (b) from SiH3
⊖ and Si3H8 and (c) from K and Si2H6 or Si3H8 in HMPT. They have been identified by 1H NMR and IR spectroscopy, and their structures are deduceable from the spectral data.
Cited by
17 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献