Cyanamid-Komplexe von Übergangsmetallen / Cyanamide Complexes of Transition Metals

Abstract

The preparation of the complexes (Ph3P)2(CO)IrNCNIr(CO)PPh3)2, (Ph3P)2Ir(CO)-NCNH, [AsPh4]2[Pd(NCNR)4] (R = H,Ph), (Ph3P)2Pd(NCNH)2 is described. The vibrational and 14N NMR spectra are reported. In the complexes [Ni(H2NCN)e]Br2, [Ni(H2NCN)4]Cl2, [Co(H2NCN)4]Cl2 the cyanamide ligand presumably is coordinated through the amino nitrogen atom.