The furfuryl alcohol (FA) resin distribution in the furfurylated bamboo

Abstract

Abstract It is well known the properties of resin impregnation wood is significantly influenced by the specific distribution pattern of resin in the modified wood. In this work, bamboo was furfurylated with an improved process. In addition to testing and evaluating its main physical, mechanical and durable properties, it was explored how the furfuryl alcohol (FA) resin is distributed in the furfurylated bamboo. To achieve this goal, scanning electron microscopy (SEM), confocal laser scanning microscopy (CLSM), nanoindentation, and imaging Fourier transform infrared microscopy (imaging FT-IR) were applied. SEM images demonstrates FA resin is mainly located in the parenchymal cell cavity of bamboo, however the existence of FA resin in the small cavities of the bamboo fibers is also observed by CLSM. In addition, the result of nanoindentation and imaging FT-IR both indicates that FA can penetrate and polymerize within the cell wall of the bamboo fiber. It is then concluded the heterogeneous but multi-scale distribution of FA resin should be responsible for the significant improvement of furfurylated bamboo in both dimensional stability and biological durability.