Cyclic Oxidation and Hot Corrosion Behavior of Nickel–Iron-Based Superalloy

Author:

Chellaganesh D.1,Adam Khan M.2,Winowlin Jappes J. T.3,Sathiyanarayanan S.4

Affiliation:

1. Department of Mechanical Engineering, Kalasalingam University, Krishnankoil, Tamil Nadu, India

2. Department of Mechanical Engineering, International Research Centre (IRC), Kalasalingam University, Krishnankoil, Tamil Nadu, India

3. Research Faculty, Mechanical Engineering, International Research Centre (IRC), Kalasalingam University, Krishnankoil, Tamil Nadu, India

4. Corrosion and Materials Protection Division, CSIR-Central Electrochemical Research Institute, Karaikudi630 003, Tamilnadu, India

Abstract

AbstractThe high temperature oxidation and hot corrosion behavior of nickel–iron-based superalloy are studied at 900 ° and 1000 °C. The significant role of alloying elements with respect to the exposed medium is studied in detail. The mass change per unit area was catastrophic for the samples exposed at 1000 °C and gradual increase in mass change was observed at 900 °C for both the environments. The exposed samples were further investigated with SEM, EDS and XRD analysis to study the metallurgical characteristics. The surface morphology has expressed the in situ nature of the alloy and its affinity toward the environment. The EDS and XRD analysis has evidently proved the presence of protective oxides formation on prolonged exposure at elevated temperature. The predominant oxide formed during the exposure at high temperature has a major contribution toward the protection of the samples. The nickel–iron-based superalloy is less prone to oxidation and hot corrosion when compared to the existing alloy in gas turbine engine simulating marine environment.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference60 articles.

1. Hot corrosion behaviour of D-gun sprayed NiCoCrAlYTa coated superalloys at 900°C in molten salt environment

2. Nickel-Based Superalloys for Advanced Turbine Engines: Chemistry, Microstructure and Properties

3. High Temperature and Materials of the The Electrochemical;Opila;Corrosion Chemistry IV Proceedings International Symposium Society USA,2003

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