Investigation of Growth Kinetics of Fe2B Layers on AISI 1518 Steel by the Integral Method

Author:

Elias-Espinosa M.1,Keddam M.2,Ortiz-Domínguez M.3,Arenas-Flores A.4,Zuno-Silva J.3,Cervantes-Sodi F.5,Reyes-Retana J. A.15

Affiliation:

1. Instituto Tecnológico y de Estudios Superiores de Monterrey-ITESM Campus Santa Fe , Av. Carlos Lazo No. 100, Del. Álvaro Obregón, CP. 01389 , México City , México

2. Laboratoire de Technologie des Matériaux, Faculté de Génie Mécanique et Génie des Procédés , USTHB , B.P. No. 32, 16111 El-Alia, Bab-Ezzouar , Algiers , Algeria

3. Universidad Autónoma del Estado de Hidalgo, Escuela Superior de Ciudad Sahagún-Ingeniería Mecánica , Carretera Cd. Sahagún-O tumba s/n, Zona Industrial CP. 43990 , Hidalgo , México

4. Centro de Investigaciones en Materiales y Metalurgia , Universidad Autónoma del Estado de Hidalgo , Ciudad Universitaria Pachuca-Tulancingo km. 4.5, Pachuca , Hidalgo , México

5. Departamento de Física y Matemáticas , Universidad Iberoamericana Ciudad de México , Prolongación Paseo de la Reforma 880, Lomas de Santa Fe, CP. 01219 , México City , México

Abstract

Abstract The AISI 1518 steel was pack-borided in the temperature range 1123–1273 K for a treatment ranging from 2 to 8 h. A compact single boride layer (Fe2B) was formed at the surface of the AISI 1518 steel using the mixture of powders composed of 20 % B4C, 10 % KBF4 and 70 % SiC. The following experimental techniques such as scanning electron microscopy coupled with EDS analysis and X-ray diffraction analysis were employed to characterize the pack-borided AISI 1518 steel. An alternative model, based on the integral mass balance equation, was used to estimate the boron diffusion coefficients in the Fe2B layers in the temperature range 1123–1273 K. Finally, the value of activation energy for boron diffusion in the AISI 1518 steel was estimated and compared with the literature data. Furthermore, the present model was validated by comparing the experimental value of Fe2B layer thickness, obtained at 1253 K for 2 h of treatment, with the predicted value.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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