Reactions of ferrocenyl chalcones with hydrazines and active methylene compounds-Reference-Cited by-同舟云学术

Reactions of ferrocenyl chalcones with hydrazines and active methylene compounds

Published:2016-04-01 Issue:2 Volume:22 Page:69-77
ISSN:2191-0197
Container-title:Heterocyclic Communications
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Author:

El-Hussieny Marwa¹,Yosef Hisham Abdallah A.¹,Mahran Mohamed R.H.¹,Ibrahim Nabila M.²

Affiliation:

1. 1Organometalloid Chemistry Department, National Research Centre, P.O. 12622, Dokki, Giza, Egypt

2. 2Organometallic and Organometalloid Chemistry Department, National Research Centre, El-Buhouth St, P.O. 12622, Dokki, Giza, Egypt

Abstract

AbstractClaisen-Schmidt condensation of ferrocenecarboxaldehyde (2b) with 2-acetylfuran (4) yielded (E)-3-ferrocenyl-1-(2-furyl)prop-2-en-1-one (E-5) together with 1,5-di(2-furyl)-3-ferrocenylpentane-1,5-dione (6). Reactions of the ferrocenyl chalcones 3a,b and 5 with hydrazine hydrate, phenyl hydrazine, ethyl acetoacetate, ethyl cyanoacetate and malononitrile, were also studied. Possible reaction mechanisms were discussed and structures of the new products were unambiguously characterized by common analytical and spectroscopic methods.

Publisher

Walter de Gruyter GmbH

Subject

Organic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/hc-2016-0006/pdf

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