Illustrating catalysis with a handmade molecular model set: catalytic oxidation of carbon monoxide over a platinum surface

Author:

Horikoshi Ryo1ORCID,Nakajima Syota1,Hosokawa Saburo2,Kobayashi Yoji3,Kageyama Hiroshi3

Affiliation:

1. Department of Environmental Science and Technology , Faculty of Design Technology, Osaka Sangyo University , Nakagaito , Daito , Osaka 574-8530 , Japan

2. Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University , 1-30 Goryo-Ohara, Nishikyo-ku , Kyoto 615-8245 , Japan

3. Department of Energy & Hydrocarbon Chemistry , Graduate School of Engineering, Kyoto University , Nishikyo-ku , Kyoto 615-8510 , Japan

Abstract

Abstract Catalytic converters (automotive catalysts) and the chemical reactions they catalyze appear in general and introductory chemistry textbooks. Although the detailed mechanisms of the chemical reactions that occur in catalytic converters have been clearly revealed via recent developments in surface and computational chemistry research, the description and illustration of the catalysis are still ambiguous in textbooks. In this paper, we describe an extracurricular lecture whereby a handmade teaching aid was employed to illustrate the basic principle of the catalytic oxidation of carbon monoxide over platinum surface, which is an essential reaction occurring in catalytic converters. The teaching aid, constructed combining easily available materials, can illustrate the positions and motions of the molecules on the platinum surface during catalytic oxidation. The lecture was favorably received by non-chemistry majors and high school students. Despite the difficulty of the topic, the audience displayed a relatively high level of understanding.

Publisher

Walter de Gruyter GmbH

Subject

Education,Chemistry (miscellaneous)

Reference31 articles.

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2. Atkins, P., Jones, L., & Laverman, L. (2013). Chemical principles: The quest for insight (6th ed.). New York: W. H. Freeman and Company.

3. Atomic radii of the elements (data page). (n.d.). Retrieved March 2021 from https://en.wikipedia.org/wiki/Atomic_radii_of_the_elements_(data page).

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5. Dumeignil, F., Paul, J.-F., & Paul, S. (2017). Heterogeneous catalysis with renewed attention: Principles, theories, and concepts. Journal of Chemical Education, 94, 675–689. https://doi.org/10.1021/acs.jchemed.6b00611.

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