Affiliation:
1. Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstraße 30, 48149 Münster, Germany
2. Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany
Abstract
Several REZnPnO phases of the ZrCuSiAs type (RE = rare earth element, Pn = P, As, Sb) were synthesized in X-ray-pure form in NaCl/KCl salt fluxes. The structure of PrZnSbO was refined from single-crystal diffractometer data: P4/nmm, a = 418.79(8), c = 946.7(5) pm, wR2 = 0.0349, 192 F2 values, 12 parameters. The REZnPnO pnictide oxides were studied with respect to magnetic susceptibility, 121Sb Mössbauer spectroscopy, and optical properties.
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16 articles.
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