Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions-Reference-Cited by-同舟云学术

Silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with malonyl peroxides in solvent-free conditions

Published:2017-05-24 Issue:1 Volume:90 Page:7-20
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:en
Short-container-title:

Author:

Bityukov Oleg V.¹²,Vil’ Vera A.¹²³,Merkulova Valentina M.¹,Nikishin Gennady I.¹,Terent’ev Alexander O.¹²³^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences , 47 Leninsky Prosp. , 119991 Moscow , Russian Federation

2. All-Russian Research Institute for Phytopathology , 143050 B. Vyazyomy, Moscow Region , Russian Federation

3. Faculty of Chemical and Pharmaceutical Technology and Biomedical Products , D. I. Mendeleev University of Chemical Technology of Russia , 9 Miusskaya Square , Moscow 125047, Russian Federation

Abstract

Abstract For the first time silica gel was observed to activate peroxides in oxidative coupling reactions. Here we report silica gel mediated oxidative C–O coupling of β-dicarbonyl compounds with cyclic diacyl peroxides affording α-acyloxy derivatives with 100% atom efficiency. The highest yields of coupling products were achieved in solvent free conditions. C–O coupling products were prepared in yields up to 86%.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2017-0312/pdf

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