Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization-Reference-Cited by-同舟云学术

Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization

Published:2017-03-01 Issue:3 Volume:89 Page:379-392
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
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Author:

Sokolov Maxim N.¹²³,Anyushin Alexander V.¹²,Hernandez-Molina Rita⁴⁵,Llusar Rosa⁶,Basallote Manuel G.⁷

Affiliation:

1. 1Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Prospekt Lavrentyeva 3, 630090 Novosibirsk, Russia

2. 2Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russia

3. 3Kazan Federal University, 18 ul. Kremlyovskaya 420008, Kazan, Russia

4. 4Departamento de Química, Unidad Departamental de Química Inorgánica, Universidad de La Laguna, La Laguna, Tenerife, Spain

5. 5Instituto Universitario de Bioorganica Antonio Gonzalez, Avda Astrofis Fco, Sanchez 2, San Cristobal la Laguna 38206, Spain

6. 6Departamento de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071 Castelló, Spain

7. 7Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, and Instituto de Biomoléculas, INBIO, Universidad de Cádiz, Avda. República Saharahui s/n, Puerto Real, 11510 Cádiz, Spain

Abstract

AbstractThis contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2017-0105/pdf

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