Application of cyclohexene oxide modified chitosan for paper preservation

Author:

Wang Xuemei123,Qi Yingping4,Shen Yongfeng4,Li Hua1

Affiliation:

1. School of Chemical Engineering , Zhengzhou University , No. 100 Science Road , Zhengzhou , Henan , China ,

2. School of Materials Science and Engineering , 34747 Shanghai University , Shanghai , China ,

3. Institute for the Conservation of the cultural heritage , 34747 Shanghai University , Shanghai , China ,

4. Zhengzhou Museum , Zhengzhou , Henan , China ,

Abstract

Abstract A new chitosan derivative (CS-CHO) was successfully synthesized based on chitosan (CS) and cyclohexene oxide (CHO). It proved that CHO was successfully grafted onto the amino group of CS by N-alkylation reaction through the characterization of FTIR, XRD and DSC-TGA. The mechanical properties (tensile strength, folding endurance, tearing strength), optical properties (whiteness, glossiness) of the CS-CHO coated paper sample were tested. The results showed that the mechanical properties of the paper treated with 10 % CS-CHO increased significantly without changing the appearance of the paper. The paper permanence (tensile strength, folding endurance, tearing strength and pH) of the treated paper samples tested by dry-heat aging test. The results showed that the permanence of the treated paper samples was significantly improved compared with the blank aged paper samples, which indicated that CS-CHO had the function of deacidification while reinforcing the paper samples, providing the possibility for deacidification and reinforcement in one-step method and playing a positive role in the paper preservation.

Publisher

Walter de Gruyter GmbH

Subject

General Materials Science,Forestry

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