Definitions and notations relating to tactic polymers (IUPAC Recommendations 2020)-Reference-Cited by-同舟云学术

Definitions and notations relating to tactic polymers (IUPAC Recommendations 2020)

Published:2020-10-02 Issue:11 Volume:92 Page:1769-1779
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:en
Short-container-title:

Author:

Fellows Christopher M.¹^ORCID,Hellwich Karl-Heinz²^ORCID,Meille Stefano V.³^ORCID,Moad Graeme⁴^ORCID,Nakano Tamaki⁵^ORCID,Vert Michel⁶^ORCID

Affiliation:

1. University of New England , Armidale , NSW 2351 , Australia

2. Beilstein-Institut zur Förderung der Chemischen Wissenschaften , Trakehner Str. 7–9, 60487 , Frankfurt , Germany

3. Politecnico di Milano , Milano , Italy

4. CSIRO Manufacturing , Clayton , VIC 3168 , Australia

5. Institute for Catalysis, Hokkaido University , Sapporo, 001-0021 , Japan

6. University of Montpellier – CNRS , 34093, Montpellier Cedex 5 , France

Abstract

Abstract This document summarizes and extends definitions and notations for the description of tactic polymers and the diad structures of which they are composed. It formally recognizes and resolves apparent inconsistencies between terminology used in the polymer field to describe tactic polymers and terminology in more common use in organic chemistry. Specifically, the terms m and r diads are recommended to replace the terms meso and racemo diads. The definitions are also updated from those in the existing Stereochemistry Document to use the term ‘stereogenic centre’, rather than ‘chiral or prochiral atoms’. Further, the terms relating to tacticity have been defined for the constituent macromolecules, rather than for the polymers composed of those macromolecules. Therefore, this document also forms an addendum and corrigendum to the 1981 document, ‘Stereochemical definitions and notations relating to polymers’.

Funder

International Union of Pure and Applied Chemistry

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2019-0409/pdf

Reference10 articles.

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3. IUPAC. Compendium of Polymer Terminology and Nomenclature (IUPAC Recommendations 2008) (the ‘Purple Book’). Prepared for publication by R. G. Jones, J. Kahovec, R. Stepto, E. S. Wilks, M. Hess, T. Kitayama, W. V. Metanomski, with advice from A. Jenkins and P. Kratochvíl, RSC Publishing, Cambridge, UK (2008).

4. G. P. Moss. Pure Appl. Chem.68, 2193 (1996).

5. IUPAC. Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 (the ‘Blue Book’). Prepared for publication by H. A. Favre and W. H. Powell, Royal Society of Chemistry, Cambridge, UK (2014); errata: https://www.qmul.ac.uk/sbcs/iupac/bibliog/BBerrors.html.

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