Ionic liquids: green solvents and reactive compounds? Reaction of tri-n-butylmethylphosphonium dimethylphosphate with elemental sulfur-Reference-Cited by-同舟云学术

Ionic liquids: green solvents and reactive compounds? Reaction of tri-n-butylmethylphosphonium dimethylphosphate with elemental sulfur

Published:2020-09-24 Issue:1 Volume:93 Page:29-37
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:en
Short-container-title:

Author:

Tarasova Natalia¹²,Krivoborodov Efrem¹,Zanin Alexey¹,Mezhuev Yaroslav¹

Affiliation:

1. D. Mendeleev University of Chemical Technology of Russia , 125047 , Moscow , Russia

2. Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry , Russian Academy of Sciences , 119017 , Moscow , Russia

Abstract

Abstract The opening of the S8 ring with the formation of linear sulfur oligomers in the presence of tri-n-butylmethylphosphonium dimethylphosphate is shown. The reaction products are separated and characterized with 1H, 13C, 31P, 17O NMR spectroscopy, HD-MS, MALDI spectroscopy and XRD. It is shown that dimethylphosphate-anion is active in the reaction, and the addition of sulfur atoms occurs via the oxygen atom of dimethylphosphate-anion. It is found that a mixture of products is formed, which differ in the number of sulfur atoms in the chain. The assumptions were made about the mechanism of interaction of sulfur with tri-n-butylmethylphosphonium dimethylphosphate.

Funder

Dmitry Mendeleev University of Chemical Technologies of Russia

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2019-0804/pdf

Reference43 articles.

1. E. A. Chernikova, L. M. Glukhov, V. G. Krasovskiy, L. M. Kustov, M. G. Vorobyeva, A. A. Koroteev. Russ. Chem. Rev.84, 875 (2015).

2. A. E. Rosamilia, C. R. Strauss, J. L. Scott. Pure Appl. Chem.79, 1869 (2007).

3. K. J. Fraser, D. R. MacFarlane. Austral. J. Chem.62, 309 (2009).

4. H. Choudhary, P. Berton, G. Gurau, A. S. Myerson, R. D. Rogers. Chem. Comm.54, 2056 (2018).

5. J. Li, S. Yang, W. Wu, H. Jiang. Eur. J. Org. Chem.11, 1284 (2018).

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Current Trends in the Synthesis of Inorganic and Organoelement Phosphorus- and Sulfur-Containing Polymers. A Review;Doklady Chemistry;2023-09

2. Nucleophilic activation of the sulfur S8 cyclic form as a green chemistry tool;Russian Chemical Bulletin;2023-02

3. Formation of Hydrogels Based on a Copolymer of N-Vinyl-2-pyrrolidone and Glycidyl Methacrylate in the Presence of the Reaction Product of 1,3-Dimethylmidazolium Dimethylphosphate and Elemental Sulfur;Gels;2022-02-21

4. Introduction to ionic liquids and their environment-friendly applications;Ionic Liquid-Based Technologies for Environmental Sustainability;2022

5. Anionic Polymerization of Ethyl 2-Cyanoacrylate Initiated by 1,3-Dimethylimidazolium (phosphonooxy-)oligosulfanide;Macromolecular Research;2021-12