2D GeSe2 amorphous monolayer

Author:

Zhang Bo1,Mikysek Tomas2,Cicmancova Veronika3,Slang Stanislav3ORCID,Svoboda Roman4,Kutalek Petr5,Wagner Tomas13

Affiliation:

1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology , University of Pardubice , Studentska 573, 532 10 Pardubice , Czech Republic

2. Department of Analytical Chemistry, Faculty of Chemical Technology , University of Pardubice , Studentska 573, 532 10 Pardubice , Czech Republic

3. Center of Materials and Nanotechnologies, Faculty of Chemical Technology , University of Pardubice , Nam. Cs. Legii 565, 530 02 Pardubice , Czech Republic

4. Department of Physical Chemistry, Faculty of Chemical Technology , University of Pardubice , Studentska 573, 532 10 Pardubice , Czech Republic

5. Joint Laboratory of Solid State Chemistry , University of Pardubice , Studentska 84, 532 10 Pardubice , Czech Republic

Abstract

Abstract In this paper, GeSe2 thin film and glass ingot were prepared in a layered structure. Subsequently, the 2D amorphous monolayers were achieved from layered thin film and layered glass ingot. The thicknesses of monolayers from thin film range from 1.5 nm to 5 nm. And the thickness of monolayer from glass ingot is 7 μm. The fast cooling of material results in the formation of self-assembled monolayers. In the case of thin film, layers are connected with “bridge”. After doping of Ag, the precipitation of nano particles exfoliates the adjacent monolayers which can be further dispersed by etching of Ag particles. In the case of glass ingot, the composition changes at 1 % between adjacent monolayers, according to EDX (energy-dispersive X-ray spectroscopy) spectra. And the glass 2D monolayer can be mechanically peeled off from the glass ingot.

Funder

Ministry of Education, Youth and Sports of Czech Republic

European Regional Development Fund

Czech Grant Agency

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

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