Affiliation:
1. Anorganische Chemie, Fluorchemie , Philipps-Universität Marburg, Hans-Meerwein-Str. 4 , D-35032 Marburg , Germany
Abstract
Abstract
This article presents an overview of recent advancements in the field of uranium chemistry, paying special attention to the preparation of starting materials and to the chemistry of uranium halides in liquid ammonia. Where suitable, insights into the chemistry of thorium are also presented. Herein, we report upon the crystal structures of several ammine complexes as well as their deprotonation products. Specific examples of hydrolysis products in liquid ammonia are showcased. Additionally, advancements in the preparation of uranium cyanides are presented.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Reference97 articles.
1. V. Doetsch, J. Jander, U. Engelhardt, C. Lafrenz, J. Fischer, H. Nagel, W. Renz, G. Türk, T. von Volkmann, G. Weber, Chemistry in nonaqueous ionizing solvents – volume I chemistry in anhydrous liquid ammonia – Part 1 Anorganische und allgemeine Chemie in flüssigem Ammoniak, Friedr. Vieweg & Sohn, Braunschweig, 1966.
2. G. F. Hüttig, Apparat zur gleichzeitigen Druck- und Raummessung von Gasen (Tensi-Eudiometer). Z. Anorg. Allg. Chem.1920, 114, 161.
3. A. Stock, E. Pohland, Tensimetrische Molekulargewichts-Bestimmungen mit flüssigem Ammoniak als Lösungsmittel. Ber. Dtsch. Chem. Ges. A/B.1925, 58, 657.
4. G. W. Watt, W. R. McBride, Ammoniates of ammonium halides. J. Am. Chem. Soc.1955, 77, 1317.
5. V. F. Hnizda, C. A. Kraus, Properties of electrolytic solutions. XXXIX. Conductance of several salts in ammonia at −34° by a precision method. J. Am. Chem. Soc.1949, 71, 1565.
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