Temperature- and moisture-dependency of CsLiB6O10. A new phase, β-CsLiB6O10-Reference-Cited by-同舟云学术

Temperature- and moisture-dependency of CsLiB6O10. A new phase, β-CsLiB6O10

Published:2014-10-24 Issue:11 Volume:229 Page:741-751
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Sennova Natalia A.,Cordier Gerhard¹,Albert Barbara¹,Filatov Stanislav K.²,Bubnova Rimma S.,Isaenko Ludmila I.³,Gubenko Lyubov I.³,Klöckner Jan-Peter⁴,Prosenc Marc H.

Affiliation:

1. Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Germany

2. Department of Crystallography, St. Petersburg State University, Russia

3. Mineralogy and Petrography Institute Branch SB RAS, Novosibirsk, Russia

4. Institut für Angewandte und Anorganische Chemie, Universität Hamburg, Germany

Abstract

Abstract The structural behavior of the non-linear optical, nanoporous compound CsLiB6O10 was studied in a wide temperature range. Both the highly anisotropic thermal expansion of the borate with temperature variation and the deterioration of its crystals were investigated. The electron density distribution was analyzed in detail. A reversible, partial transition to a new modification, β-CsLiB6O10, was observed during cooling crystalline and moist samples of CsLiB6O10 to –25 °C. The crystal structure of the new phase is described.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2014-1758/pdf

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