Affiliation:
1. I.V.Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials of the Kola Science Center , RAS, Apatity , Russia
2. Saint Petersburg State University , Saint Petersburg , Russia
Abstract
Abstract
Binary complex compounds (BCC) [Rh(en)3][Fe(CN)6]·2H2O (I) and [Rh(en)3][Co(CN)6]·2H2O (II) have been prepared and characterized by the X-ray diffraction, crystal optic, elemental and thermal analyses. The crystal structures I and II (space group P21/n) are described within the monoclinic crystal system, are insular and isostructural. The thermal behavior of BCC I and II is identical, with an exception of a higher temperature (~by 50°C) of II decomposition. In air atmosphere, the ligand removal is followed by the formation of, respectively, Rh+1/2Fe2O3 and Rh+Co that on further heating up to 1000°C convert into RhFeO3 and RhCoO1.5. The residues of annealing at 1000°C in argon atmosphere are Rh+1/2Fe2O3 and Rh+CoO, respectively.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Reference18 articles.
1. S. V. Korenev, A. B. Venedictov, Yu. V. Shubin, S. A. Gromilov, K. V. Yusenko, J. Struct. Chem.2003, 44, 46.
2. A. V. Zadesenets, E. Yu. Filatov, K. V. Yusenko, Yu. V. Shubin, S. V. Korenev, Inorg. Chim. Acta.2008, 361, 199.
3. S.F. Martynova, K. V. Yusenko, I. V. Korolkov, I. A. Baidina, S. V. Korenev, J. Struct. Chem.2009, 50, 120.
4. Yu. V. Shubin, Dissertation for the degree of Dr. Sc. in Chemistry, INKh SB RAS, Novossibirsk, 2009.
5. Sh.-Zh. Zhan, K.-B. Yu, J. Liu, Inorg. Chem. Commun.2006, 9, 1007.
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