The crystal structure of hibbingite, orthorhombic Fe2Cl(OH)3-Reference-Cited by-同舟云学术

The crystal structure of hibbingite, orthorhombic Fe2Cl(OH)3

Published:2019-02-23 Issue:6 Volume:234 Page:379-382
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Zubkova Natalia V.¹,Pekov Igor V.¹,Sereda Evgeny V.²,Yapaskurt Vasiliy O.¹,Pushcharovsky Dmitry Yu.¹

Affiliation:

1. Faculty of Geology, Lomonosov Moscow State University , Vorobievy Gory , 119991 Moscow , Russia

2. Norilskgeologiya , PO Box 889 , 663330 Talnakh, Norilsk, Krasnoyarsk Krai , Russia

Abstract

Abstract The crystal structure of hibbingite, natural γ-Fe2+ 2Cl(OH)3, a mineral of the atacamite group, was studied on a sample from the Oktyabr’sky mine, Norilsk district, Siberia, Russia. The structure was solved by direct methods based on single crystal X-ray diffraction data and refined to R=2.07% [520 reflections with I>2σ(I)]. The mineral is isostructural with atacamite and is orthorhombic, Pnma, a=6.3373(2), b=6.9892(2), c=9.3457(3) Å, V=413.95(3) Å3, Z=4. The structure contains Fe(1)(OH)4Cl2 octahedra which share Cl–O(1) edges to form chains running along the b axis and cross-linked by the chains of Fe(2)(OH)5Cl octahedra sharing O(2)–O(2) edges and running along the a axis.

Funder

Russian Science Foundation

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2018-2124/pdf

Reference18 articles.

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