Structural studies on copper and nitrogen doped nanosized anatase

Author:

Martinelli Alberto1,Alberti Stefano2,Caratto Valentina2,Lova Paola2,Locardi Federico2,Pampararo Giovanni2,Villa Silvia2,Ferretti Maurizio12

Affiliation:

1. CNR-SPIN , corso F.M. Perrone 24 , 16152 Genova , Italy

2. Department of Chemistry and Industrial Chemistry , University of Genova , Via Dodecaneso 31 , 16146 Genova , Italy

Abstract

Abstract Pure TiO2, N- and Cu-doped and double-doped (Cu, N) samples were synthesized via sol–gel route in order to investigate the local and average structure of the crystalline TiO2 synthesized under different pH conditions. Samples are mainly constituted of anatase phase, even though low but significant amounts of secondary brookite grew in most samples. A detailed structural characterization was performed by means of synchrotron X-ray elastic scattering experiments; structural data of the different samples were obtained by means of the Rietveld refinement, whereas insights about their local structure were gained by means of the pair distribution analysis.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

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