Elucidating the physical properties of the molybdenum oxide Mo4O11 and its tantalum substituted variant Mo2Ta2O11-Reference-Cited by-同舟云学术

Elucidating the physical properties of the molybdenum oxide Mo4O11 and its tantalum substituted variant Mo2Ta2O11

Published:2020-04-17 Issue:4-5 Volume:235 Page:143-155
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Zoller Michael¹,Bubnova Rimma²,Biryukov Yaroslav²,Haussühl Eiken³,Pöttgen Rainer⁴,Janka Oliver⁴,Penner Simon⁵,Praty Corsin⁵,Fitzek Harald⁶,Winkler Jörg⁷,Filatov Stanislav⁸,Huppertz Hubert¹

Affiliation:

1. Institut für Allgemeine, Anorganische und Theoretische Chemie , Universität Innsbruck , Innrain 80–82 , A-6020 Innsbruck , Austria

2. Institute of Silicate Chemistry, Russian Academy of Sciences , Makarov Emb. 2 , 199034 Saint Petersburg , Russia

3. Institut für Geowissenschaften , Goethe-Universität Frankfurt , Altenhöferallee 1 , D-60438 Frankfurt a. M. , Germany

4. Institut für Anorganische und Analytische Chemie , Universität Münster , Corrensstraße 30 , D-48149 Münster , Germany

5. Institut für Physikalische Chemie , Universität Innsbruck , Innrain 52c , A-6020 Innsbruck , Austria

6. Institute of Electron Microscopy and Nanoanalysis, NAWI Graz , Graz University of Technology , Steyrergasse 17 , A-8010 Graz , Austria

7. Plansee SE , Metallwerk-Plansee-Straße 71 , A-6600 Reutte , Austria

8. Institute of Earth Sciences, Department of Crystallography , Saint Petersburg State University , Universiteskaya Emb. 7/9 , 199034 St. Petersburg , Russia

Abstract

Abstract Although γ/η-Mo4O11 and Mo2Ta2O11 are used in a variety of industrial applications and can easily be synthesized in a chemical vapour transport (CVT) process or reactions in silica ampoules, respectively, only few data are available concerning their physical properties. In this paper, we further explore the properties of the three compounds with respect to their thermal and magnetic behavior, surface composition, and Raman spectroscopic properties.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2019-0073/pdf

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