Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides-Reference-Cited by-同舟云学术

Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides

Published:2018-10-16 Issue:3 Volume:234 Page:141-153
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Kovrugin Vadim M.¹²,Colmont Marie²,Siidra Oleg I.¹³,Charkin Dmitry O.⁴,Aliev Almaz²,Krivovichev Sergey V.¹⁵,Mentré Olivier²

Affiliation:

1. Department of Crystallography , St. Petersburg State University , 199034 St. Petersburg , Russian Federation

2. Unité de Catalyse et Chimie du Solide (UCCS) , UMR 8181 CNRS, Université Lille 1 Sciences et Technologies , 59655 Villeneuve d’ASCQ , France

3. Nanomaterials Research Center, Kola Science Center, Russian Academy of Sciences , 184200 Apatity , Russian Federation

4. Inorganic Chemistry Division, Department of Chemistry , Moscow State University , GSP-1, 119991 Moscow , Russian Federation

5. Kola Science Center, Russian Academy of Sciences , 184209 Apatity , Russian Federation

Abstract

Abstract Single crystals of new Mn2[Bi2O](SeO3)4 (I), MnBi(SeO3)2Cl (II), MnIIMnIII(SeO3)2Cl (III), Mn5(SeO3)2Cl6 (IV), and Mn4(Mn5,Bi)(SeO3)8Cl5 (V) have been synthesized by chemical vapour transport and hydrothermal methods. They have been structurally characterized by single crystal X-ray diffraction analysis. The compounds II–V are the first Mn selenite chlorides, while the I, II and V compounds are the first Bi-containing Mn oxoselenites. Structural relationships of the new phases with other compounds are discussed. An overview of the mixed-ligand MnO m Cl n polyhedra in inorganic compounds is given.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2018-2088/pdf

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