Author:
Weber Marcus,Schlesinger Maik,Walther Markus,Zahn Dirk,Schalley Christoph A.,Mehring Michael
Abstract
AbstractInvestigations on bismuth oxido clusters are focused on the nucleation and growth processes towards large cluster motifs and their stability in the gas phase, which has been studied by electrospray ionization mass spectrometry (ESI-MS), molecular dynamics (MD) simulations and X-ray scattering experiments evaluated by pair distribution function (PDF) analysis. The formation of metastable bismuth(III) oxides was obtained by hydrolysis of polynuclear bismuth oxido clusters and subsequent thermal treatment under non-equilibrium conditions. Temperature dependent PXRD and Raman spectroscopic experiments gave insight into the formation process of metastable β-Bi
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Reference148 articles.
1. Salicylate-functionalized bismuth oxido clusters: hydrolysis processes and microbiological activity;Eur. J. Inorg. Chem.,2014
2. Synthesis and structure of Bi14O20(SO4), a new bismuth oxide sulfate;Chem. Mater.,1998
3. Molecular mechanisms of [Bi6O4(OH)4](NO3)6 precursor activation, agglomeration, and ripening towards bismuth oxide nuclei;Eur. J. Inorg. Chem.,2015
4. Synthesis, ethanolysis, and hydrolysis of bismuth(III) ortho-nitrobenzoate complexes en route to a pearl necklace-like polymer of Bi10 oxo-clusters;Organometallics,2009
5. Hydrolysis of a basic bismuth nitrate-formation and stability of novel bismuth oxido clusters;Chem. Eur. J.,2011
Cited by
21 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献