Facile isolation of a stable S6-symmetric methanol hexamer using the guest-free microporous metal-organic framework: zinc 5-tert-butyl isophthalate-Reference-Cited by-同舟云学术

Facile isolation of a stable S6-symmetric methanol hexamer using the guest-free microporous metal-organic framework: zinc 5-tert-butyl isophthalate

Published:2018-01-19 Issue:6 Volume:233 Page:429-435
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Jovial Samaila A.¹²,Raftery James²,Anderson Michael W.¹²,Attfield Martin P.¹²

Affiliation:

1. Centre for Nanoporous Materials, The University of Manchester , Brunswick Street , Manchester, M13 9PL , UK

2. School of Chemistry, The University of Manchester , Brunswick Street , Manchester, M13 9PL , UK

Abstract

Abstract The ordered structure of the guest-free microporous metal-organic framework zinc 5-tert-butyl isophthalate {Zn[(CH3)3CC6H3(CO2)2]} has been determined and shown to be easily loaded with methanol to form {Zn[(CH3)3CC6H3(CO2)2]}·CH3OH. The methanol forms a S6-symmetric hexamer within the pores of the material that is uniquely defined by the void space and exerts a subtle structural effect on the framework structure of the host. The work demonstrates the use of this type of metal-organic framework as a matrix to isolate unique molecular clusters in a facile manner.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2017-2090/pdf

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