Fibril formation through self-assembly of a simple glycine derivative and X-ray diffraction study

Author:

Dutta Arpita1,Das Suven2,Das Purak2,Maity Suvendu3,Ghosh Prasanta3

Affiliation:

1. Department of Chemistry , Rishi Bankim Chandra Evening College , Naihati, 24-Parganas (N) , Pin-743165 , India

2. Department of Chemistry , Rishi Bankim Chandra College for Women , Naihati, 24-Parganas (N) , Pin-743165 , India

3. Department of Chemistry , R K Mission Residential College , Narendrapur, Kolkata-103 , India

Abstract

Abstract N-(N-benzoyl glycinyl)-N,N′-dicyclohexylurea was synthesised by conjugating N-benzoyl glycine and dicyclohexylcarbodiimide (DCC) using triethylamine as base catalyst. A single crystal X-ray diffraction study reveals that the compound self-assembles into a supramolecular sheet structure by intermolecular N–H · · · O, C–H · · · O hydrogen bonding and non-bonding van der Waals interactions. A high resolution transmission electronic microscopic (HR-TEM) image of the compound exhibits formation of fibrils in the solid state.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference20 articles.

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4. J. F. Vincent, J. D. Currey, The Mechanical Properties of Biological Materials, Cambridge University Press, Cambridge, 1980.

5. J. -M. Lehn, Angew. Chem. Int. Ed. Engl.1988, 27, 89.

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