The influence of SrCl2 on the corrosion behavior of magnesium

Author:

Cao Fuyong1,Zhang Jing1,Song Xin1,Chen Jinhua1,Ying Tao2,Song Guang-Ling134ORCID

Affiliation:

1. Center for Marine Materials Corrosion and Protection, College of Materials , Xiamen University , 422 Siming Road, Siming District , Xiamen , Fujian , P.R. China

2. National Engineering Research Center of Light Alloy Net Forming, School of Materials Science and Engineering , Shanghai Jiao Tong University , Shanghai , P.R. China

3. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering , Xiamen University , Xiamen , P.R China

4. Department of Ocean Science and Engineering , Southern University of Science and Technology , Shenzhen , Guangdong 518055 , P.R China

Abstract

Abstract The influence of SrCl2 on the corrosion behavior of magnesium (Mg) in 3.5 wt.% NaCl was evaluated by immersion testing, electrochemical measurement and the examination of the corrosion morphology. A small addition of SrCl2 decreased the corrosion rate of Mg. In contrast, an excess of SrCl2 increased the corrosion rate of Mg, even higher than that in 3.5 wt.% NaCl. There is a competition effect of the SrCl2 on the corrosion behavior of Mg in 3.5 wt.% NaCl. The Sr2+ can improve the protection of corrosion product film through the formation of SrCO3. While the Cl can damage the protection of the corrosion product film. The Mg specimen achieved the best corrosion resistance in 3.5 wt.% NaCl + 0.005 mol L−1 SrCl2.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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