Trivalent Gd incorporated Zn2SiO4 phosphor material for EPR and luminescence investigations

Author:

Singh Vijay1ORCID,Bhatia Kanika2,Rao Allam Srinivasa2,Joo Ji Bong1

Affiliation:

1. Department of Chemical Engineering , Konkuk University , Seoul 05029 , Republic of Korea

2. Department of Applied Physics , Delhi Technological University , Bawana Road , New Delhi , 110 042 , India

Abstract

Abstract Zn2SiO4:Gd3+ powder was obtained by the sol–gel preparation technique and then characterized by using Fourier-transform infrared spectroscopy and X-ray diffraction techniques. The sample exhibited photoluminescence in the ultraviolet spectral zone with a maximum emission wavelength of 314 nm. Ultraviolet emission in the range of 305–320 nm is also called ultraviolet-B emission. This UV range emission is used in lamps for skin treatment and phototherapy. The electron paramagnetic resonance spectrum recorded for the Zn2SiO4:0.015Gd3+ phosphor revealed g values of 3.46, 2.64, and 2.20, confirming the presence of Gd3+ ions in the small ligand field. Furthermore, Gd3+ ions attain tetrahedral symmetry in the prepared host compound.

Publisher

Walter de Gruyter GmbH

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