A Voltammetric Technique Using A Modified Carbon Paste Electrode For The Determination Of Aclonifen

Author:

Novotný Vít12,Barek Jiří2

Affiliation:

1. Institute for Nanomaterials, Advanced Technology and Innovation, Bendlova 1407/7, 461 17 Liberec, Czech Republic, phone +420485353876

2. Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Faculty of Science, Charles University of Prague, Hlavova 2030, Praha 2, Czech Republic

Abstract

Abstract A method for the determination of aclonifen at a carbon paste electrode modified with tricresyl phosphate has been developed. The optimum electrochemical regime proved to be differential pulse voltammetry (DPV) in the negative potential range from −200 to −1600 mV. The optimum pH for the determination proved to be pH = 8. The calibration dependence is linear and the limit of detection achieved for the method was 2·10−6 mol/dm3. The method is fast, reliable and it is suitable for the detection of aclonifen in the concentration range from 2·10−6 to 1·10−4 mol/dm3.

Publisher

Walter de Gruyter GmbH

Subject

Environmental Chemistry,Environmental Engineering

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