Darstellung und Molekülstruktur des Ferrocenylkomplexes CpW(NO)2Fc und seine Oxidation zu CpWO2Fc/Synthesis and Molecular Structure of the Ferrocenyl Complex CpW(NO)2Fc and its Oxidation to CpWO2Fc-Reference-Cited by-同舟云学术

Darstellung und Molekülstruktur des Ferrocenylkomplexes CpW(NO)2Fc und seine Oxidation zu CpWO2Fc/Synthesis and Molecular Structure of the Ferrocenyl Complex CpW(NO)2Fc and its Oxidation to CpWO2Fc

Published:1986-11-01 Issue:11 Volume:41 Page:1431-1436
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Herberhold Max¹,Kniesel Heidemarie¹,Haumaier Ludwig¹,Gieren Alfred²³,Ruiz-Péreza Catalina²

Affiliation:

1. Laboratorium für Anorganische Chemie der Universität Bayreuth, Universitätsstraße 30, D-8580 Bayreuth

2. Max-Planek-Institut für Biochemie, Arbeitsgruppe für Chemische Kristallographie, Am Klopferspitz, D-8033 Martinsried

3. Institut für Anorganische und Analytische Chemie, Universität Innsbruck, Österreich

Abstract

Abstract The σ-ferrocenyl complex CpW (NO)2Fc (1) was prepared from CpW (NO)2Cl and ferrocenyl lithium, and oxidized by air in CH2Cl2 solution to give CpWO2Fc (2). An X-ray crystal structure analysis of 1 indicated the presence of two almost linear nitrosyl groups (with W -N -O angles of 173.0(9) and 175.4(7)°). The W -C (ferrocenyl) bond length is 2.164(10) Å.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1986-1118/pdf

Cited by 18 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations;Dalton Trans.;2010

2. (η5-C5H5)-Ring alkylation reaction with the C5H5 anion: towards the construction of tri-Fe complex Fe{[μ,η5:η4-5-exo-(1′-C5H4)C5H5]Fe(CO)2(PPh3)}2;Journal of Organometallic Chemistry;2001-12

3. Ferrocenediyl-Bridged Triiron Complexes;Organometallics;2001-05-01

4. Heterobimetallische Vanadium- und Thallium-2-(dimethylaminomethyl)ferrocenyl-Verbindungen;Monatshefte f�r Chemie Chemical Monthly;1997-04

5. Structure and Reactivity of (η-C5R5)Mo(NO)2−Halide, −Halomethyl, and −Alkyl Complexes: Consecutive Aerobic Methylene and Nitrosyl Ligand Oxidation;Organometallics;1996-05-14