Microwave Spectra of Dimethylether (CH3)2O and (CD3)2O in Excited Torsional States-Reference-Cited by-同舟云学术

Microwave Spectra of Dimethylether (CH3)2O and (CD3)2O in Excited Torsional States

Published:1978-12-01 Issue:12 Volume:33 Page:1498-1510
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Lutz H.¹,Dreizler H.¹

Affiliation:

1. Abt. Chemische Physik im Institut für Physikalische Chemie der Universität Kiel

Abstract

Abstract The rotational spectra of the torsional excited states v̅n = 11,12,21, 22, 23 have been measured and assigned. The torsional fine structure was used to determine the coefficients V3 and V' 12 of the hindering potential. For (CH3)2O : V3 = 2618 ± 4 cal/mole, V'12 = 18 ± 8 cal/mole, for (CD3)2O : V3 = 2572 ± 6 cal/mole, V'12 = 29 ± 12 cal/mole, V12 was correlated to V3 .

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1978-1214/pdf

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