Carbon nanodot with highly localized excitonic emission for efficient luminescent solar concentrator

Abstract

Abstract Luminescent solar concentrators (LSCs) are attractive for the easy operation and high compatibility with building integrated photovoltaics due to their low cost, large-scale and applicability. However, underutilized sunlight in visible wavelengths often impedes the advance of LSCs. Here, we demonstrate an orange-emitting carbon nanodots-based LSC (O-CDs) with excitation concentrated in the visible wavelengths. The orange-emitting carbon nanodots (O-CDs) with highly localized excitonic emission are prepared via atomic condensation of doped pyrrolic nitrogen, delivering a high photoluminescence quantum yield of 80 % and a suitable Stokes shift with absorption spectrum situated in the visible region. The O-CDs are embedded in polyvinylpyrrolidone to obtain a highly transparent, stable and environmentally friendly O-CDs-based LSC. Thanks to efficient utilization of solar radiation in visible areas and well match between the emission of O-CDs and the response bands of photovoltaic cells, the O-CDs-based LSC reveals an optical conversion efficiency of 5.17 %, superior to that of most carbon nanodots-based LSCs. These results provide an effective strategy to develop carbon-based luminescent concentrated materials for architectural integrated photovoltaic technology.