Dielectric dual-dimer metasurface for enhanced mid-infrared chiral sensing under both excitation modes

Abstract

Abstract Chirality (C) is a fundamental symmetry property of objects. Detecting and distinguishing molecular chirality in the infrared spectrum is important in life sciences, biology, and chemistry. In this paper, we demonstrate an achiral metasurface based on a gaped dual-germanium-dimer array for enhanced mid-infrared chiral sensing under both circularly polarized light (CPL) and linearly polarized light (LPL) excitations. With the metasurface, strong electric and magnetic dipole resonances with large field enhancement can be generated, resulting in an accessible superchiral hotspot in the dimer gaps under both excitation modes. The maximum electric and magnetic field enhancements exceed 220 and 100 for the bare metasurface, and exceed 70 and 60 for the metasurface coated with a 50 nm chiral biolayer under both excitations, respectively. Importantly, a high volume-averaged C enhancement C E_ave of 241 (444) and C E_ave_bio of 161 (102) under CPL (LPL) excitation can be achieved for the bare metasurface and it coated with the chiral biolayer, respectively. These results may open up new possibilities for ultrasensitive vibrational circular dichroism (VCD) and rotational optical dispersion (ORD) spectroscopy in the mid-infrared range.