Molecular scale nanophotonics: hot carriers, strong coupling, and electrically driven plasmonic processes

Author:

Zhu Yunxuan1ORCID,Raschke Markus B.2ORCID,Natelson Douglas3ORCID,Cui Longji4ORCID

Affiliation:

1. Department of Physics and Astronomy , 3990 Rice University , Houston , TX , USA

2. Department of Physics, and JILA , 1877 University of Colorado Boulder , Boulder , CO , USA

3. Department of Physics and Astronomy, Electrical and Computer Engineering, Materials Science and Nanoengineering , 3990 Rice University , Houston , TX , USA

4. Department of Mechanical Engineering, Materials Science and Engineering Program, & Center for Experiments on Quantum Materials (CEQM) , 1877 University of Colorado Boulder , Boulder , CO , USA

Abstract

Abstract Plasmonic modes confined to metallic nanostructures at the atomic and molecular scale push the boundaries of light–matter interactions. Within these extreme plasmonic structures of ultrathin nanogaps, coupled nanoparticles, and tunnelling junctions, new physical phenomena arise when plasmon resonances couple to electronic, exitonic, or vibrational excitations, as well as the efficient generation of non-radiative hot carriers. This review surveys the latest experimental and theoretical advances in the regime of extreme nano-plasmonics, with an emphasis on plasmon-induced hot carriers, strong coupling effects, and electrically driven processes at the molecular scale. We will also highlight related nanophotonic and optoelectronic applications including plasmon-enhanced molecular light sources, photocatalysis, photodetection, and strong coupling with low dimensional materials.

Funder

National Science Foundation

Air Force Research Laboratory

Office of Naval Research Global

Welch Foundation

Publisher

Walter de Gruyter GmbH

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