Effectiveness factor of two-dimensional ring-shaped catalyst pellets

Author:

Asif Mohammad1,Ibrahim Ahmed A.1,Mohammed Yahya A.1,Al-Ghurabi Ebrahim H.1

Affiliation:

1. King Saud University , Department of Chemical Engineering , PO Box 800, Riyadh 11421 , KSA

Abstract

Abstract The use of hollow catalytic support improves the utilization of the catalytic material because of the absence of the pellet core, and moreover ensures low reactor pressure drop owing to enhanced bed voidage. In this study, the expressions for the efficient computation of the effectiveness factor are derived for a ring-shaped catalyst pellet undergoing first-order irreversible reaction. The methodology consists of using solutions of one-dimensional problems to remove non-homogeneous boundary conditions. The expressions obtained exhibit significantly faster convergence behavior than those reported in literature. The shape parameters, namely, the height-to-diameter ratio and the inner-to-outer radii ratio, significantly affect the catalyst utilization, such that several-fold improvement in the effectiveness factor is achievable.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry,Biotechnology

Reference21 articles.

1. 1. Morbidelli, M., Servida, A. & Varma, A. (1982). Optimal catalyst activity profiles in pellets. 1. The case of negligible external mass transfer resistance. Ind. Eng. Chem. Fundam. 21(3), 278–284. DOI: 10.1021/i100007a015.10.1021/i100007a015

2. 2. Wu, H., Brunovska, A., Morbidelli, M. & Varma, A. (1990). Optimal catalyst acitivity profiles in pellets—VIII. General nonisothermal reacting systems with arbitrary kinetics. Chem. Eng. Sci. 45(7), 1855–1862. DOI: 10.1016/0009-2509(90)87061-V.10.1016/0009-2509(90)87061-

3. 3. Wu, H., Yuan, Q. & Zhu, B. (1990). An experimental study of optimal active catalyst distribution in pellets for maximum selectivity. Ind. Eng. Chem. Res. 29(9), 1771–1776. DOI: 10.1021/ie00105a006.10.1021/ie00105a006

4. 4. Baratti, R., Gavriilidis, A., Morbidelli, M. & Varma, A. (1994). Optimization of a nonisothermal nonadiabatic fixed-bed reactor using dirac-type silver catalysts for ethylene epoxidation. Chem. Eng. Sci. 49(12), 1925–1936. DOI: 10.1016/0009-2509(94)80077-4.10.1016/0009-2509(94)80077-4

5. 5. Morbidelli, M., Gavriilidis, A. & Varma, A. (2001). Catalyst design, optimal distribution of catalyst in pellets, reactors, and membranes (1st ed.). Cambridge, U.K.: Cambridge University Press.

Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3