Metalltrifluorphosphin-Komplexe, XXXI / Metaltrifluorophosphine Complexes, XXXI

Abstract

Fe (PF3) 5 reacts with halogens to yield the dihalogeno-tetrakis (trifluorophosphine) -iron complexes X2Fe (PF3)4 (X = Cl, Br, J). The structure of the volatile cristalline compounds is octahedral with the halogen atoms in cis-position. The IR-, Mass- and F-NMR-spectra are reported and discussed; the Mössbauer-spectra are listed.