Determination of impurity distributions in ingots of solar grade silicon by neutron activation analysis

Author:

Karches Barbara1,Schön Jonas2,Gerstenberg Heiko3,Hampel Gabriele1,Krenckel Patricia2,Plonka Christian1,Ponsard Bernard4,Riepe Stephan2,Stieghorst Christian1,Wiehl Norbert5

Affiliation:

1. Institute for Nuclear Chemistry , Johannes Gutenberg University of Mainz , D-55128 Mainz , Germany

2. Fraunhofer Institute for Solar Energy Systems , D-79110 Freiburg , Germany

3. Heinz-Maier-Leibniz Zentrum , Technische Universität München , D-85748 Garching , Germany

4. Belgian Nuclear Research Centre (SCK•CEN) , BR2 reactor , B-2400 Mol , Belgium

5. Institute for Nuclear Chemistry , Johannes Gutenberg University of Mainz , D-55128 Mainz , Germany , Tel.: +49 6131 3924507, Fax: +49 6131 3925253

Abstract

Abstract In a series of crystallization experiments, the directional solidification of silicon was investigated as a low cost path for the production of silicon wafers for solar cells. Instrumental neutron activation analysis was employed to measure the influence of different crystallization parameters on the distribution of 3d-metal impurities of the produced ingots. A theoretical model describing the involved diffusion and segregation processes during the solidification and cooling of the ingots could be verified by the experimental results. By successive etching of the samples after the irradiation, it could be shown that a layer of at least 60 μm of the samples has to be removed to get real bulk concentrations.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Chemical analysis with neutrons;Non-Destructive Material Characterization Methods;2024

2. Gettering in silicon photovoltaics: A review;Solar Energy Materials and Solar Cells;2022-01

3. Determination of boron and hydrogen in materials for multicrystalline solar cell production with prompt gamma activation analysis;Journal of Radioanalytical and Nuclear Chemistry;2018-04-27

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