Synthesis of porous resorcinol-formaldehyde resins and study of their sorption characteristics toward Cs in highly mineralized alkaline media-Reference-Cited by-同舟云学术

Synthesis of porous resorcinol-formaldehyde resins and study of their sorption characteristics toward Cs in highly mineralized alkaline media

Published:2019-04-11 Issue:12 Volume:107 Page:1145-1153
ISSN:2193-3405
Container-title:Radiochimica Acta
language:en
Short-container-title:

Author:

Egorin Andrei¹²,Tokar Eduard¹²,Palamarchuk Marina²,Portnyagin Arseniy¹²,Tutov Mikhail¹²,Mis’ko Daria¹,Kalashnikova Anastasia¹,Sokolnitskaya Tatiana²,Tananaev Ivan¹²

Affiliation:

1. Far Eastern Federal University , Sukhanova St. 8 , Vladivostok 690000 , Russia

2. Institute of Chemistry, Far East Branch, Russian Academy of Sciences , Pr. Stoletiya Vladivostoka 159 , Vladivostok 690022 , Russia

Abstract

Abstract The present work was devoted to study of sorption parameters of resorcinol-formaldehyde resins synthesized through introduction of an inorganic filler (in amounts of 10 and 25 wt.%) with its subsequent leaching. The surface morphology and composition of ion-exchange resins have been investigated by means of the method of scanning electron microscopy. The effect of internal diffusion on the peculiarities of the ion-exchange process has been determined. It has been revealed that the ion-exchangers destruction upon a prolonged contact with highly alkaline solutions is followed by the decrease of internal diffusion coefficients and selectivity toward Cs-137 micro-quantities. The sorption properties of resins under dynamic conditions at high solution feeding rates have been studied. A sample with the highest efficiency of Cs-137 removal from highly mineralized solutions has been identified.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/ract-2018-3046/pdf

Reference23 articles.

1. Logunov, M. V., Karpov, V. I., Druzhinina, N. E., Tananaev, I. G.: Approaches to treatment of highly active pulps accumulated at FSUE PA “Mayak”. Voprosy Radiatsionnoy Bezopasnosti. 1, 15 (2011) [In Russian].

2. Logunov, M. V., Karpov, V. I., Tananaev, I. G.: Stabilization of thermal-physical conditions of survey of some storage tanks for highly active pulps at FSUE PA “Mayak”. Voprosy Radiatsionnoy Bezopasnosti. 4, 18 (2011) [In Russian].

3. Improvements of Radioactive Waste Management at WWER Nuclear Power Plants. IAEA-TECDOC–1492. International Atomic Energy Agency, Waste Technology Section, Vienna, Austria, p. 95 (2006).

4. Prout, W. E., Russell, E. R., Groh, H. J.: Ion exchange absorption of cesium by potassium hexacyanocobalt (II) ferrate (II). J. Inorg. Nucl. Chem. 27, 473 (1965).10.1016/0022-1902(65)80367-0

5. Milyutin, V. V., Mikheev, S. V., Gelis V. M., Kozlitin E. A.: Sorption of cesium on ferrocyanide sorbents from highly saline solutions. Radiochemistry 51, 298 (2009).10.1134/S1066362209030151

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Removal of Cs-137 Radionuclide by Resorcinol–Formaldehyde Ion-Exchange Resins from Solutions Simulating Real Liquid Radioactive Waste;Molecules;2022-12-15