Statistical Modeling, Optimization and Kinetics of Mn2+ Adsorption in Aqueous Solution Using a Biosorbent

Author:

Tajari Elaheh1,Langeroodi Narges Samadani2,Khalafi Mahnaz3

Affiliation:

1. Department of Chemistry , Faculty of Sciences, Golestan University , Gorgan , Iran

2. Department of Chemistry , Faculty of Sciences, Golestan University , Gorgan , Iran , e-mail:

3. Department of Statistics , Faculty of Sciences, Golestan University , Gorgan , Iran

Abstract

Abstract This paper describes the adsorption of Mn2+ ions from water with a mixture of wheat bran and Japanese medlar core shell (weight ratio of 30–70 wheat bran to Japanese medlar core shell) as low-cost adsorbent. Scanning Electron Microscope was used to characterize the adsorbent. The response surface methodology (RSM) that is usually approximated by a second-order regression model was employed to evaluate the effects of solution pH, initial Mn2+ concentration, adsorbent weight and contact time on the removal ratio of the Mn2+ ions. In this regard, the significant variables initial Mn2+ ions concentration, pH, adsorbent weight and square pH were found based on the small P-value for the model coefficients. The predicted optimal conditions were also performed. In the process optimization, maximal value of the removal ratio of Mn2+ was achieved as 96.91%. Additionally, this paper discusses the kinetic of adsorption in optimal conditions.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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