Ni-Fe-Cr-Oxides: An Efficient Catalyst Activated by Visible Light for the Oxygen Evolution Reaction

Author:

Krysiak Olga A.12,Cichowicz Grzegorz3,Conzuelo Felipe1,Cyranski Michal K.3,Augustynski Jan4

Affiliation:

1. Analytical Chemistry – Center for Electrochemical Sciences (CES), Faculty of Chemistry and Biochemistry , Ruhr University Bochum , Universitätsstr. 150 , D-44780 Bochum , Germany

2. College of Inter-Faculty Individual Studies in Mathematics and Natural Sciences , University of Warsaw , S. Banacha 2c , 02-097, Warsaw , Poland

3. Czochralski Laboratory of Advanced Crystal Engineering, Biological and Chemical Research Centre, Department of Chemistry , University of Warsaw , Żwirki i Wigury 101 , 02-089, Warsaw , Poland

4. Centre of New Technologies , University of Warsaw , S. Banacha 2c , 02-097, Warsaw , Poland

Abstract

Abstract The oxygen evolution reaction (OER) is a thermodynamically and kinetically demanding process, therefore it requires the use of catalysts enabling to meet technologically relevant conditions. Here, we realized efficient OER catalysts fabricated using relatively cheap precursors consisting of earth-abundant metal oxides, i.e. nickel, iron, and chromium, and a simple one-step preparation method. It is shown that the catalyst is activated by anodic polarization under irradiation with visible light, which allows decreasing the overpotential necessary for the OER.

Funder

NCN Poland

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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