Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement-Reference-Cited by-同舟云学术

Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement

Published:2017-12-21 Issue:7-8 Volume:232 Page:1017-1039
ISSN:2196-7156
Container-title:Zeitschrift für Physikalische Chemie
language:en
Short-container-title:

Author:

Weigl Peter¹,Talluto Vincenzo²,Walther Thomas²,Blochowicz Thomas¹

Affiliation:

1. Institute of Solid State Physics, TU Darmstadt , Darmstadt , Germany

2. Institute of Applied Physics, TU Darmstadt , Darmstadt , Germany

Abstract

Abstract We have developed a flexible experimental setup to conduct triplet solvation dynamics (TSD) experiments. The setup is capable of exciting dyes at 355, 320 and 266 nm. Phosphorescence spectra can be recorded up to a 10 ns-resolution usually covering three decades using a grating spectrograph and a CCD camera. In this contribution, we describe the experimental setup as well as first investigations on water-alcohol mixtures, microemulsions and new dyes for TSD, i.e. naphthalene derivates, which take full advantage of this experimental method sensitive to the local environment of the dyes.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/zpch-2017-1024/pdf

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