Studying Media Polarity Effects on the Photo-Physical Behaviors of Organometallic Complexes with Azo-Containing Schiff-Base Ligands

Abstract

Abstract Solvent molecules as an important factor can modify the photo-physical behavior of organometallic complexes. For precise investigation, in this paper, the spectral behavior of some groups of copper complexes with different substituents were studied in various solvent media. In this case, the linear solvation energy relationships concept was used for determination of various contribution of media induced specific and non-specific interactions on the photo-physical behavior of various forms of organometallic complexes with azo-containing Schiff-base dyes. Moreover, the calculated dipole moments indicate that samples with different forms tend to have polar structure in the excited state as compared to those in the ground state. By exploiting of calculated dipole moments and obtained quantitative results in the ground and excited states, the dominant solvent induced resonance structures were also estimated. The obtained experimental results can give more information about how these samples can behave in various physical, chemical and biological phenomena.